Controlling surface porosity of graphene-based printed aerogels
Loading...
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Springer Nature
Department of Engineering
https://doi.org/10.1038/s41699-022-00312-w
Department of Engineering
https://doi.org/10.1038/s41699-022-00312-w
Abstract
Description
The surface porosity of graphene-based aerogels strongly influences their performance in applications involving mass transfer. However, the factors determining the surface porosities are not well-understood, hindering their application-specific optimisation. Here, through experiments and hydrodynamic simulations, we show that the high shear stress during the graphene-based aerogel fabrication process via 3D printing leads to a non-porous surface. Conversely, crosslinking of the sheets hinders flake alignment caused by shearing, resulting in a porous surface. Our findings enable fine control of surface porosity of printed graphene-oxide aerogels (GOA) through regulation of the crosslinking agents and shear stress. Using this strategy, we demonstrate the performance advantages of GOA with porous surface over their non-porous counterpart in dye adsorption, underscoring the importance of surface porosity in certain application scenarios.
EP/T014601/1
EP/T014601/1